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Chemisorption and Reactivity on Supported Clusters and Thin Films:

Towards an Understanding of Microscopic Processes in Catalysis

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Proceedings of the NATO Advanced Study Institute, Erice, Trapani, Sicily, July 15-26, 1996


Titel: Chemisorption and Reactivity on Supported Clusters and Thin Films:
Autoren/Herausgeber: R.M. Lambert, Gianfranco Pacchioni (Hrsg.)
Aus der Reihe: NATO Science Series E
Ausgabe: Softcover reprint of hardcover 1st ed. 1997

ISBN/EAN: 9789048148073

Seitenzahl: 532
Format: 24 x 16 cm
Produktform: Taschenbuch/Softcover
Gewicht: 825 g
Sprache: Englisch

Heterogeneous catalysis provides the backbone of the world's chemical and oil industries. The innate complexity of practical catalytic systems suggests that useful progress should be achievable by investigating key aspects of catalysis by experimental studies on idealised model systems. Thin films and supported clusters are two promising types of model system that can be used for this purpose, since they mimic important aspects of the properties of practical dispersed catalysts. Similarly, appropriate theoretical studies of chemisorption and surface reaction clusters or extended slab systems can provide valuable information on the factors that underlie bonding and catalytic activity. This volume describes such experimental and theoretical approaches to the surface chemistry and catalytic behaviour of metals, metal oxides and metal/metal oxide systems. An introduction to the principles and main themes of heterogeneous catalysis is followed by detailed accounts of the application of modern experimental and theoretical techniques to fundamental problems. The application of advanced experimental methods is complemented by a full description of theoretical procedures, including Hartree-Fock, density functional and similar techniques. The relative merits of the various approaches are considered and directions for future progress are indicated. - Newsletter
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